Zeitschrift für Naturforschung / A / 31 (1976)

نویسنده

  • L. Waldmann
چکیده

Recently a reciprocity theorem has been derived from the transport-relaxation equations for a simple system, consisting of one medium (Ref . ' ) . With a composite system, consisting of two immiscible media in contact, a plausible generalized reciprocity scheme, here called universal reciprocity postulate, is suggested now. It leads to an equivalent reciprocity requirement at the interface between both media and thus decisively restricts — in form of provable Onsager relations — the possible constitutive laws connecting the thermodynamical forces and fluxes at the interface. For the formulation of these ideas, some mathematical tools are developed in advance. Finally, heat conduction is treated, as the most simple example, first in the direct way, then according to the more sophisticated mathematical tools.

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تاریخ انتشار 2013